Sulfonato-encapsulated bismuth(III) oxido-clusters from Bi2O3 in water under mild conditions.
نویسندگان
چکیده
Treatment of Bi(2)O(3) with the acids; S-(+)-10-camphorsulfonic, 2,4,6-mesitylenesulfonic and sulfamic, under sonication at room temperature in water for 2-4 h, results in the formation and subsequent crystallisation of polynuclear bismuth oxido-clusters; [Bi(18)O(12)(OH)(12)(O(3)S-Cam)(18)(H(2)O)(2)], [Bi(38)O(45)(O(3)S-Mes)(24)(H(2)O)(14)] and [Bi(6)O(4)(OH)(4)(O(3)SNH(2))(6)].
منابع مشابه
Metastable β-Bi2O3 Nanoparticles with Potential for Photocatalytic Water Purification Using Visible Light Irradiation
Invited for this month's cover is the group of Prof. Michael Mehring. The cover picture shows the degradation of the model dye rhodamine B (RhB) in water using β-Bi2O3 nanoparticles as photocatalyst, which was prepared from pre-organized bismuth oxido clusters. For more details, see the Full Paper on p. 146 ff.
متن کاملMetastable β-Bi2O3 nanoparticles with high photocatalytic activity from polynuclear bismuth oxido clusters.
The synthesis of nanoscaled β-Bi(2)O(3) starting from the bismuth oxido clusters [Bi(6)O(4)(OH)(4)](NO(3))(6)·H(2)O, [Bi(22)O(26)(OSiMe(2)(t)Bu)(14)], [Bi(38)O(45)(NO(3))(20)(DMSO)(28)](NO(3))(4)·4DMSO and [Bi(38)O(45)(OMc)(24)(DMSO)(9)]·2DMSO·7H(2)O (OMc = O(2)CC(3)H(5)) under ambient conditions is reported. The metal oxido clusters are regarded as ideal precursors for β-Bi(2)O(3) due to their...
متن کاملGraphical Abstract: ChemistryOpen 4/2013
The cover picture shows the degradation of the model dye rhodamine B (RhB) in water using b-Bi2O3 nanoparticles as photocatalyst, which was prepared from preorganized bismuth oxido clusters. In the background, a homemade photoreactor for in situ studies is shown, including the decolorizing process of the aqueous RhB solution as observed during visible light irradiation. The catalytic cycle show...
متن کاملCover Picture: Metastable β-Bi2O3 Nanoparticles with Potential for Photocatalytic Water Purification Using Visible Light Irradiation (ChemistryOpen 4/2013)
COVER PICTURE Maik Schlesinger, Marcus Weber, Steffen Schulze, Michael Hietschold, and Michael Mehring* The cover picture shows the degradation of the model dye rhodamine B (RhB) in water using β-Bi2O3 nanoparticles as photocatalyst, which was prepared from preorganized bismuth oxido clusters. In the background, a homemade photoreactor for in situ studies is shown, including the decolorizing pr...
متن کاملMetastable β-Bi2O3 Nanoparticles with Potential for Photocatalytic Water Purification Using Visible Light Irradiation
Photocatalytic studies under visible light irradiation using nanosized β-Bi2O3 are reported. β-Bi2O3 nanoparticles are prepared starting from the well-defined bismuth oxido cluster [Bi38O45(OMc)24(DMSO)9]⋅2 DMSO⋅7 H2O (OMc=O2CC3H5) using a straightforward hydrolysis and annealing protocol. Powder X-ray diffraction studies, transmission electron microscopy, diffuse reflectance UV/Vis spectroscop...
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 61 شماره
صفحات -
تاریخ انتشار 2012